High-frequency monitoring of hydrological and biogeochemical fluxes in forested catchments of southern Chile

The variability of rainfall-dependent streamflow at catchment scale modulates many ecosystem processes in wet temperate forests. Runoff in small mountain catchments is characterized by a quick response to rainfall pulses which affects biogeochemical fluxes to all downstream systems. In wet-temperate climates, water erosion is the most important natural factor driving downstream soil and nutrient losses from upland ecosystems. Most hydrochemical studies have focused on water flux measurements at hourly scales, along with weekly or monthly samples for water chemistry. Here, we assessed how water and element flows from broad-leaved, evergreen forested catchments in southwestern South America, are influenced by different successional stages, quantifying runoff, sediment transport and nutrient fluxes during hourly rainfall events of different intensities. Hydrograph comparisons among different successional stages indicated that forested catchments differed in their responses to high intensity rainfall, with greater runoff in areas covered by secondary forests (SF), compared to old-growth forest cover (OG) and dense scrub vegetation (CH). Further, throughfall water was greatly nutrient enriched for all forest types. Suspended sediment loads varied between successional stages. SF catchments exported 455 kg of sediments per ha, followed by OG with 91 kg/ha and CH with 14 kg/ha, corresponding to 11 rainfall events measured from December 2013 to April 2014. Total nitrogen (TN) and phosphorus (TP) concentrations in stream water also varied with rainfall intensity. In seven rainfall events sampled during the study period, CH catchments exported less nutrients (46 kg/ha TN and 7 kg/ha TP) than SF catchments (718 kg/ha TN and 107 kg/ha TP), while OG catchments exported intermediate sediment loads (201 kg/ha TN and 23 kg/ha TP). Further, we found significant effects of successional stage attributes (vegetation structure and soil physical properties) and catchment morphometry on runoff and sediment concentrations, and greater nutrients retention in OG and CH catchments. We conclude that in these southern hemisphere, broad-leaved evergreen temperate forests, hydrological processes are driven by multiple interacting phenomena, including climate, vegetation, soils, topography, and disturbance history.     

Luminescence dating of sand–loess sequences and response of Mu Us and Otindag sand fields (north China) to climatic changes

The sand–loess transition zone in north China is sensitive to climate change, and is an ideal place to investigate past environmental changes. However, past climate change at millennial–centennial timescales in this region has not been well reconstructed because of limited numerical dating. Alternations of sandy loam soils with aeolian sand layers in the Mu Us and Otindag sand fields, which lie along the sand–loess transition zone, indicate multiple intervals of dune activity and stability. This change is probably a response to variations of the East Asian monsoon climate during the late Quaternary. The single aliquot regeneration (SAR) optically stimulated luminescence (OSL) dating protocol, which has been successfully applied to aeolian deposits worldwide, is applied to these two sand fields in this study. The OSL ages provide reliable constraints for reconstruction of past climate changes at suborbital timescale. Sections in both sand fields contain aeolian sand beds recording millennial‐scale episodes of dry climate and widespread dune activation, including episodes at about the same time as Heinrich Event 5 and the Younger Dryas in the North Atlantic region. These results demonstrate the potential of aeolian sediments in semi‐arid north China to record millennial‐scale climatic events, and also suggest that dry–wet climate variation at the desert margin in China may be linked to climatic change elsewhere in the Northern Hemisphere, through atmospheric circulation. This article was published online on 27 November 2008. An error was subsequently identified. This notice is included in the online and print versions to indicate that both have been corrected (16 December 2008). Copyright © 2008 John Wiley & Sons, Ltd.     

Southern Meridional Atmospheric Circulation Associated with IOD

Using the monthly wind and sea surface temperature （SST） data, southern meridional atmospheric circulation cells associated with the Indian Ocean Dipole Mode （IOD） events in the Indian Ocean are for the first time described and examineS. The divergent wind and pressure vertical velocity are employed for the identification of atmospheric circulation cells. During the four different phases of the positive IOD events, the anomalous meridional Hadley circulation over the western Indian Ocean shows that the air rises in the tropics, flows poleward in the upper troposphere, sinks in the subtropics, and returns back to the tropics in the lower troposphere. The anomalous Hadley circulation over the eastern Indian Ocean is opposite to that over the western Indian Ocean. During positive IOD events, the meridional Hadley circulation over the eastern Indian Ocean is weakened while it is strengthened over the western Indian Ocean. Correlation analysis between the IOD index and the indices of the Hadley cells also proves that, the atmospheric circulation patterns are evident in every IOD event over the period of record.     

The Upper Pleistocene to Holocene sediments on the Mediterranean island of Lampedusa (Italy)

The island of Lampedusa lies on the northern edge of the African continental shelf, but during some Quaternary marine lowstands it was joined to the African continent. The study and dating of the aeolian, alluvial, detrital sediments, calcareous crusts and speleothems have established that the climatic–environmental variations recorded on the island can be related chronologically to those known for northern Libya, Tunisia and the Italian peninsula. During the Last Glacial Maximum, phases of Saharan dust accumulation on Lampedusa occurred, and were coeval with dust accumulation in crater lakes and on high mountains in central‐southern Italy, and with phases of glacial advance in the Apennines and in the Alps. During the late Holocene, accumulation of Saharan dust on Lampedusa occurred but there was little accumulation of dust on the northern side of the Mediterranean Sea. With the new data from Lampedusa, it is possible to envisage two different scenarios of atmospheric circulation relating to the Last Glacial Maximum and to the late Holocene. During the Last Glacial Maximum, southerly atmospheric circulation brought rainfall to the southern slopes of the Alps and to the Apennines. During the late Holocene, a prevalent westerly atmospheric circulation became established in the northern Mediterranean. Copyright © 2004 John Wiley & Sons, Ltd.     

The solubility of iron sulphides in synthetic and natural waters at ambient temperature

A critical evaluation of literature values for the solubility products, K _sp ^NBS = [Fe²⁺][HS^–] Fe²⁺ HS^– (H _NBS ⁺ )^–1, of various iron sulphide phases results in consensus values for the pKs of 2.95 ± 0.1 for amorphous ferrous sulphide, 3.6 ± 0.2 for mackinawite, 4.4 ± 0.1 for greigite, 5.1 ± 0.1 for pyrrhotite, 5.25 ± 0.2 for troilite and 16.4 ± 1.2 for pyrite.Where the analogous ion activity products have been measured in anoxic freshwaters in which there is evidence for the presence of solid phase FeS, the values lie within the range of 2.6–3.22, indicating that amorphous iron sulphide is the controlling phase. The single value for a groundwater of 2.65 (2.98 considering carbonate complexation) agrees. In seawater four values range between 3.85 to 4.2, indicating that mackinawite or greigite may be the controlling phase. The single low value of 2.94 is in a situation where particularly high fluxes of Fe (II) and S (–II) may result in the preferential precipitation of amorphous iron sulphide. Formation of framboidal pyrite in these sulphidic environments may occur in micro-niches and does not appear to influence bulk concentrations. Calculations show that the formation of Fe₂S₂ species probably accounts for very little of the iron or sulphide in most natural waters. Previously reported stability constants for the formation of Fe (HS)₂ and (Fe (HS)₃)^– are shown to be suspect, and these species are also thought to be negligible in natural waters. In completely anoxic pore waters polysulphides also have a negligible effect on speciation, but in tidal sediments they may reach appreciable concentrations and lead to the direct formation of pyrite. Concentrations of iron and sulphide in pore waters can be controlled by the more soluble iron sulphide phase. The change in the IAP with depth within the sediment may reflect ageing of the solid phase or a greater flux of Fe (II) and S (–II) nearer the sediment surface. This possible kinetic influence on the value of IAPs has implications for their use in geochemical studies involving phase formation.     

新生代6次陨击事件研究及存在问题

陨击事件对古生物灭绝、古气候、古地质环境演化有重要影响。结合我们在陨击事件方面的新研究成果,探讨了新生代6次主要陨击事件的研究动态及存在问题。近几年来,一些新的陨击证据被进一步发现,有的微玻璃陨石场的分布范围进一步扩大,有的相关源陨击坑的研究取得了新的进展,当然,还有一些难解之谜需要进一步探讨。